If you have a bog standard current account, with a normal Debit card it should work.
However, if you have one of the newer accounts, especially if transactions have to be cleared by a third party, or your bank only issues a cash card, then it is unlikely to work.
There are now very many of these newer type of accounts, which are especially attractive to younger people but Motabiliy has not yet caught up .
Someone at Motability needs to take ownership of this problem and get it sorted!